Splet09. nov. 2024 · NH 3 temperature-programmed desorption (NH 3-TPD) is frequently used for probing the nature of the active sites in CuSSZ-13 zeolite for selective catalytic reduction (SCR) of NO x.Herein, we propose an interpretation of NH 3-TPD results, which takes into account the temperature-induced dynamics of NH 3 interaction with the active centers. It … SpletThis technique allows the study of both the acidity density and the distribution of acid site strengths. Such “strength profile” was obtained by plotting the relative rate of desorbed …
TPD of NH3 profiles for HZSM-5 and USY zeolites - ResearchGate
Splet26. sep. 2024 · Temperature-programmed desorption (TPD) is one of the most straightforward surface science experiments for the determination of the thermodynamic and kinetic parameters of a reaction. In our previous study (J. Phys. Chem. C, 2013, 117, 6136-6142), we proposed a model combining DFT methods with microkinetics to … http://www.sylzyhg.com/EN/1005-2399/current.shtml scallops butter
New method for the study of surface acidity of zeolites by NH3-TPD …
Splet01. jul. 2024 · The nature of the active sites was characterized by BET, TEM, H2‐TPR, and NH3‐TPD. Characterization results revealed that acidity and the redox properties of the catalysts play an important role in achieving high activity for NH3‐SCR reaction. The highest catalytic activity of Cu/ZSM‐5 can be correlated to easy reducibility of Cu ... SpletWe developed a procedure for aqueous ion exchange to obtain different Cu loadings of Cu/SAPO-34 (between 0 and 2.6 wt %.) The catalysts were washcoated on monoliths and characterised with respect to their activity and selectivity under standard selective catalytic reduction (SCR), fast SCR, NH3 oxidation and NO oxidation reactions. They were further … Splet我是一个搞碳一化学的新手,实验室以前也都没有做过这方面的东西,什么东西都要自己来,我看了好多文献上的方法但是都是非常模糊的,有比较详细的也是测分子筛酸度的nh3-tpd,我现在非常希望有哪位老师能提供一套完整的操作计算方法给我(测催化剂还原度和分散度等的),相信对那些长期 ... scallops butternut squash recipe